Reactivity Series and Metal Extraction: Question 1
Syllabus 9.4
A materials engineer tests small offcuts of three metals (magnesium, zinc and iron) by dropping an identical-sized piece of each into separate beakers containing the same volume and concentration of dilute hydrochloric acid. Every beaker starts at . The highest temperature reached in each beaker during the next two minutes is recorded: magnesium reaches , zinc reaches , and iron reaches .
Based on this data, what is the correct order of these three metals, from most reactive to least reactive?
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Worked solution
Step 1: Link temperature change to reactivity
The reaction between a metal and dilute hydrochloric acid is exothermic. The more reactive a metal is, the faster and more vigorously it reacts, and the more thermal energy it releases into the acid in a given time. So a bigger temperature rise (in the same time, with the same volume and concentration of acid) is evidence of a more reactive metal.
Step 2: Compare the recorded values
Since every beaker started at , the temperature rises were:
- Magnesium:
- Zinc:
- Iron:
Step 3: Rank the metals
Ordering these rises from largest to smallest gives:
So, from most reactive to least reactive: magnesium, zinc, iron. This also matches their known positions in the reactivity series.
Why the other options are wrong
- B (zinc, magnesium, iron): swaps zinc and magnesium, but magnesium produced the largest temperature rise, so it must be listed first.
- C (iron, zinc, magnesium): this is the order reversed, least reactive to most reactive, not most to least.
- D (magnesium, iron, zinc): swaps zinc and iron, but zinc’s rise () was clearly greater than iron’s ().
Final answer
- The correct order, most to least reactive, is magnesium, zinc, iron, option A.