Reactivity Series and Metal Extraction: Question 1

Syllabus 9.4

Multiple choice Core 1 mark

A materials engineer tests small offcuts of three metals (magnesium, zinc and iron) by dropping an identical-sized piece of each into separate beakers containing the same volume and concentration of dilute hydrochloric acid. Every beaker starts at 20°C20\,°\text{C}. The highest temperature reached in each beaker during the next two minutes is recorded: magnesium reaches 52°C52\,°\text{C}, zinc reaches 38°C38\,°\text{C}, and iron reaches 26°C26\,°\text{C}.

Based on this data, what is the correct order of these three metals, from most reactive to least reactive?

Choose an answer to check it, then compare with the worked solution below.

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Worked solution

The reaction between a metal and dilute hydrochloric acid is exothermic. The more reactive a metal is, the faster and more vigorously it reacts, and the more thermal energy it releases into the acid in a given time. So a bigger temperature rise (in the same time, with the same volume and concentration of acid) is evidence of a more reactive metal.

Step 2: Compare the recorded values

Since every beaker started at 20°C20\,°\text{C}, the temperature rises were:

  • Magnesium: 5220=32°C52 - 20 = 32\,°\text{C}
  • Zinc: 3820=18°C38 - 20 = 18\,°\text{C}
  • Iron: 2620=6°C26 - 20 = 6\,°\text{C}

Step 3: Rank the metals

Ordering these rises from largest to smallest gives:

magnesium(32°C)>zinc(18°C)>iron(6°C)\text{magnesium} (32\,°\text{C}) > \text{zinc} (18\,°\text{C}) > \text{iron} (6\,°\text{C})

So, from most reactive to least reactive: magnesium, zinc, iron. This also matches their known positions in the reactivity series.

Why the other options are wrong

  • B (zinc, magnesium, iron): swaps zinc and magnesium, but magnesium produced the largest temperature rise, so it must be listed first.
  • C (iron, zinc, magnesium): this is the order reversed, least reactive to most reactive, not most to least.
  • D (magnesium, iron, zinc): swaps zinc and iron, but zinc’s rise (18°C18\,°\text{C}) was clearly greater than iron’s (6°C6\,°\text{C}).

Final answer

  • The correct order, most to least reactive, is magnesium, zinc, iron, option A.