Kinetic Particle Model of Matter: Question 10
Syllabus 2.1.3
A fixed mass of gas is kept at a constant temperature. Its pressure, , is measured for several different volumes, , and a graph of (on the y-axis) against (on the x-axis) is plotted. What is the shape of this graph?
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Worked solution
Step 1: Start from the pressure–volume law
For a fixed mass of gas at constant temperature:
Step 2: Rearrange in terms of
Dividing both sides by :
Step 3: Recognise the form of this equation
This has the form , where , a straight-line equation () with gradient and no constant term added on. A graph of against is therefore a straight line whose gradient equals the constant (), and which passes through the origin, because when , .
Step 4: Match to the options
This matches option A.
Why the other options are wrong
| Option | Problem |
|---|---|
| B | The equation has no added constant, so the line must pass through the origin, not miss it. |
| C | A curve approaching both axes is the shape of plotted directly against (not against ). |
| D | A horizontal line would mean pressure never changes with volume, which contradicts . |
Final answers
- A graph of against for a fixed mass of gas at constant temperature is a straight line through the origin, option A.