Worked solution
Part (a): Show that the half-life is about 12.5 hours
The decay constant and half-life are related by:
t1/2=λln2
Substituting the given value:
t1/2=1.54×10−50.6931=4.501×104 s
Converting to hours (dividing by 3600 s h−1):
t1/2=36004.501×104=12.50 h
Recompute as a check, working backwards: if t1/2=12.50 h=4.500×104 s, then λ=ln2/t1/2=0.6931/(4.500×104)=1.54×10−5 s−1, matching the given decay constant.
So t1/2≈12.5 hours, as required to show.
Part (b): Initial number of undecayed nuclei
Activity and the number of undecayed nuclei are related by A=λN, so at t=0:
N0=λA0=1.54×10−58.00×1010
N0=5.195×1015
Recompute as a check using a different split of the powers of ten: 1.548.00=5.195, and 10−51010=1015, giving the same N0=5.195×1015.
N0=5.19×1015 nuclei (3 s.f.)
Part (c): Activity after 24.0 hours
First convert the elapsed time to seconds, since λ is in s−1:
t=24.0 h×3600 s h−1=8.64×104 s
Activity obeys the same exponential decay law as the number of nuclei:
A=A0e−λt
The exponent is:
λt=1.54×10−5×8.64×104=1.331
So:
A=8.00×1010×e−1.331=8.00×1010×0.2643
A=2.115×1010 Bq
Recompute as a check using the half-life instead: 24.0 h is 24.0/12.50=1.920 half-lives, so A=A0×(0.5)1.920=8.00×1010×0.2644=2.115×1010 Bq, the two methods agree.
A=2.11×1010 Bq (3 s.f.)
Final answers
- (a) t1/2≈12.5 hours
- (b) N0=5.19×1015 nuclei
- (c) A=2.11×1010 Bq